
Nowadays, particle size characterization has been
widely used in many industrial process and quality control, as well
as academic researches. In many applications, however, a simple size
analysis assuming spherical particles is not sufficient since product
properties and process parameters are often also related to particle
shape. More detailed particle shape analysis is often required especially
in pharmaceutical and toner industries.
The most common method to perform shape analysis of particulate samples
is image analysis in which particle shape information is obtained
through analysis of projected image of individual particles.
There are many parameters can be used in characterizing shape of particles.
Some are direct measures and some are shape descriptors of individual
particles.
The following are the common measured parameters:
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Equivalent Circular Area Diameter: the diameter of a circle with its area equals to the projected area of the particle. |
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Least Bounding Circle: the smallest circle that encloses the particle. |
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Least Feret Diameter: the smallest distance between 2 parallel lines that do not intersect the particle. |
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Greatest Feret Diameter: the largest distance between 2 parallel lines that do not intersect the particle. |
| Least Bounding Rectangle Width (Length): the maximum width (length) of the particle enclosed by a rectangle. | |
| Fiber Length (Width): the average of actual length (width) of fiber. |
The following are the common descriptors:
Sphericity: the “circularity” of particle with the value
between 0 and 1, with 1 representing a perfect circle. It is determined
from measured area A and perimeter P, using the equation 4?A / P2.
A perfect circle has sphericity of 1 while a very ‘spiky’
or irregular object has circularity closer to 0. Sphericity is sensitive
to both overall form (like elongation) and surface roughness (like
convexity).
Elongation: a measure of the length width relationship. It is defined
as 1-[width/length]. Shapes symmetrical in all axes such as circles
or squares have similar length and width (elongation close to 0).
Needle-shaped particles have length > width (elongation closer
to 1). Elongation not affected by surface roughness for a given width/length.
Convexity: a measure of the surface roughness of a particle. It is
defined as convex hull perimeter/actual particle perimeter. Convex
hull is defined as area enclosed by an imaginary elastic band surrounding
shape. Smooth shapes have a convexity of 1 while very ‘spiky’
or irregular objects have a convexity closer to 0. Unlike elongation,
convexity is a measure of surface roughness and is unaffected by aspect
ratio.